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Bis[1,1'-(1,3-phenyl-enedimethyl-ene)di(1H-imidazol-3-ium)] ?-octa-molybdate.

ABSTRACT: In the title compound, (C(14)H(16)N(4))(2)[Mo(8)O(26)], the ?-octa-molybdate anion is centrosymmetric. N-H?O hydrogen bonds link the diimidazolium cations and the polyoxidoanions into a chain structure along [100]. ?-? inter-actions between the imidazole rings and between the imidazole and benzene rings [centroid-centroid distances = 3.611?(2) and 3.689?(3)?Å, respectively] connect the chains.

SUBMITTER: Wang XD

PROVIDER: S-EPMC3254318 | biostudies-other | 2012 Jan

REPOSITORIES: biostudies-other

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Bis[1,1'-(1,3-phenyl-enedimethyl-ene)di(1H-imidazol-3-ium)] β-octa-molybdate.

Wang Xiao-Dan XD Hou Guang-Feng GF Yu Ying-Hui YH Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20111214 Pt 1

In the title compound, (C(14)H(16)N(4))(2)[Mo(8)O(26)], the β-octa-molybdate anion is centrosymmetric. N-H⋯O hydrogen bonds link the diimidazolium cations and the polyoxidoanions into a chain structure along [100]. π-π inter-actions between the imidazole rings and between the imidazole and benzene rings [centroid-centroid distances = 3.611 (2) and 3.689 (3) Å, respectively] connect the chains. ...[more]

PMID: 22259350

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