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Bis(?-2-carb-oxy-5-nitro-benzoato-?O:O)bis-[(2,2'-bipyridine-?N:N')chloridocopper(II)] dihydrate.

ABSTRACT: The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(II) cation is penta-coordinated within a distorted square-pyramidal environment defined by a two ?(2)-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01[Formula: see text]) by O-H?O and O-H?Cl hydrogen bonds.

SUBMITTER: Wang H

PROVIDER: S-EPMC3274844 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Bis(μ-2-carb-oxy-5-nitro-benzoato-κO:O)bis-[(2,2'-bipyridine-κN:N')chloridocopper(II)] dihydrate.

Wang Hui H

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(II) cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ(2)-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and on ...[more]

PMID: 22346893

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