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Poly[(?(4)-5-bromo-pyridine-3-sulfonato)-silver(I)].

ABSTRACT: The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra-hedral geometry. The Ag(I) ions are linked by ?(4)-5-bromo-pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C-H?Br hydrogen-bonding inter-actions into a three-dimensional supra-molecular network. The Ag?Ag separation is 3.0159?(6)?Å, indicating the presence of argentophilic inter-actions.

SUBMITTER: Lu YB

PROVIDER: S-EPMC3274848 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Poly[(μ(4)-5-bromo-pyridine-3-sulfonato)-silver(I)].

Lu Ying-Bing YB Jian Fang-Mei FM

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

The silver(I) complex, [Ag(C(5)H(3)BrNO(3)S)](n), was obtained by reaction of AgNO(3) and 5-bromopyridine-3-sulfonic acid. The Ag(I) ion is coordinated by an O(3)N donor set in a slightly distorted tetra-hedral geometry. The Ag(I) ions are linked by μ(4)-5-bromo-pyridine-3-sulfonate ligands, forming a layer parallel to (100). The layers are further connected via C-H⋯Br hydrogen-bonding inter-actions into a three-dimensional supra-molecular network. The Ag⋯Ag separation is 3.0159 (6) Å, indicatin ...[more]

PMID: 22346795

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