Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(benzyl-trimethyl-ammonium) di-?-bromido-bis-[dibromido-mercurate(II)].

ABSTRACT: In the crystal structure of the title compound, (C(10)H(16)N)(2)[Hg(2)Br(6)], the condensed anion consists of two edge-sharing HgBr(4) tetrahedra and is situated on a centre of symmetry. The anions are linked to the cations through weak C-H?Br inter-actions.

SUBMITTER: Jin L

PROVIDER: S-EPMC3274863 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis(benzyl-trimethyl-ammonium) di-μ-bromido-bis-[dibromido-mercurate(II)].

Jin Lei L

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

In the crystal structure of the title compound, (C(10)H(16)N)(2)[Hg(2)Br(6)], the condensed anion consists of two edge-sharing HgBr(4) tetrahedra and is situated on a centre of symmetry. The anions are linked to the cations through weak C-H⋯Br inter-actions. ...[more]

PMID: 22346810

Similar Datasets

Bis(butyl-triethyl-ammonium) di-?-bromido-bis-[dibromido-mercurate(II)].

Project description:In the title mol-ecular salt, (C(10)H(24)N)(2)[Hg(2)Br(6)], the complete anion is generated by crystallographic inversion symmetry, forming a pair of edge-sharing HgBr(4) tetra-hedra. In the crystal, the cations and anions are linked by weak C-H?Br inter-actions.

| S-EPMC3344377 | biostudies-literature

Poly[bis(phenethyl-ammonium) [di-bromido-plumbate(II)]-di-μ-bromido]].

Project description:Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl-formamide (DMF) using nitro-methane as the poor solvent. This perovskite-type organic-inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr(6) octa-hedra separated by bilayers of phenethyl-ammonium cations. The octa-hedra are rotated and tilted due to N-H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra-chloridoplumbate (C(6)H(5)C(2)H(4)NH(3))(2)[PbCl(4)].

| S-EPMC2970995 | biostudies-literature

Bis(benzyl-trimethyl-ammonium) tetra-bromidocuprate(II).

Project description:In the title mol-ecular salt, (C(10)H(16)N)(2)[CuBr(4)], the Cu(II) ion adopts a squashed tetra-hedral geometry with Br-Cu-Br angles varying between 99.29 (3) and 132.53 (3)°. In the crystal, the components are linked by C-H⋯Br inter-actions, thereby generating a three-dimensional network.

| S-EPMC3200753 | biostudies-literature

Bis(benzyl-trimethyl-ammonium) dichromate(VI).

Project description:The asymmetric part of the title compound, (C(10)H(16)N)(2)[Cr(2)O(7)], contains one cation and a half of the dichromate dianion, which has a staggered conformation and exhibits disorder of the bridging O atom around the inversion center over two positions in a 1:1 ratio. Weak inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional structure.

| S-EPMC3246999 | biostudies-literature

Bis(benzyl-ammonium) di-hydrogen diphosphate.

Project description:The asymmetric unit of the title salt, 2C6H5CH2NH3 (+)·H2P2O7 (2-), contains two independent benzyl-ammonium cations and a di-hydrogen diphosphate dianion. In the crystal, O-H?O and N-H?O hydrogen bonds link the cations and anions, forming a two-dimensional network parallel to (010). Within this network, weak C-H?O hydrogen bonds are observed.

| S-EPMC3914045 | biostudies-literature

Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-?-bromido-dibromido-plumbate(II)]].

Project description:The title compound, {(C(8)H(20)N(2))[PbBr(4)]}(n), crystallizes as an inorganic-organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr(6) octa-hedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr(6) octa-hedra and the organic cation exhibit symmetry. The cations inter-act via N-H?Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.

| S-EPMC2979491 | biostudies-other

Di-?-bromido-bis-[bromido(di-2-pyridylmethane-diol-?N,N')copper(II)] dihydrate.

Project description:The centrosymmetric title complex, [Cu(2)Br(4)(C(11)H(10)N(2)O(2))(2)]·2H(2)O, was one of three complexes isolated by slow evaporation of an acetonitrile reaction mixture of CuBr(2) with di-2-pyridyl ketone (1:1 molar ratio). The title complex contains a 1:1 metal-to-ligand ratio of copper(II) with the hydrated form of the ligand di-2-pyridylmethane-diol. The copper centers are bridged by bromide donors, leading to a Cu-Cu distance of 4.090?(6)?Å. The crystals form as non-merohedral twins with two components related by a 180° rotation around the normal to [100]; the selected sample had a twin ratio of 0.63:0.37.

| S-EPMC2960647 | biostudies-literature

Bis(trimethyl-phenyl-ammonium) tetra-bromidocuprate(II).

Project description:The crystal structure of the title compound, (C(9)H(14)N)(2)[CuBr(4)], consists of two quarternary ammonium cations and a tetra-hedral cuprate anions. Weak C-H⋯Br hydrogen bonding is present between the cation and anion in the crystal structure.

| S-EPMC2979935 | biostudies-literature

Bis(2-meth-oxy-benzyl-ammonium) di-aqua-bis-(di-hydrogen diphosphato-?(2) O,O')manganate(II) dihydrate.

Project description:The asymmetric unit of the title compound, (C8H12NO)2[Mn(H2P2O7)2(H2O)2]·2H2O, consists of half an Mn(II) complex anion, a 2-meth-oxy-benyl-ammonium cation and a solvent water mol-ecule. The Mn(II) complex anion lies across an inversion center, and has a slightly distorted octa-hedral coordination environment for the Mn(II) ion, formed by two bidentate dihydrogendiphosphate ligands and two water mol-ecules. In the crystal, the components are linked by O-H?O and N-H?O hydrogen bonds, forming layers parallel to (100). An intra-molecular N-H?O hydrogen bond is also observed.

| S-EPMC3884241 | biostudies-literature

catena-Poly[trimethyl-phenyl-ammonium [[bromidocad-mate(II)]-μ-bromido-μ-chlorido]].

Project description:In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.

| S-EPMC2983584 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data