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Bis(10-meth-oxy-benzo[h]quinolinium) tetra-chloridozinc.

ABSTRACT: In the title compound, (C(14)H(12)NO)(2)[ZnCl(4)], the benzo[h]quinolinium groups are approximately planar, with maximum deviations of 0.049?(8) and 0.056?(9)?Å. The meth-oxy groups are stabilized by intra-molecular N-H?O hydrogen bonds. The structure also exhibits weak inter-molecular N-H?Cl hydrogen bonds between the cations and anions. ?-? inter-actions are present between the pyridinium and benzene rings [centroid-centroid distances = 3.640?(4), 3.728?(5) and 3.628?(5)?Å].

SUBMITTER: Dong Z

PROVIDER: S-EPMC3274869 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Bis(10-meth-oxy-benzo[h]quinolinium) tetra-chloridozinc.

Dong Zhenming Z Liu Bo B

Acta crystallographica. Section E, Structure reports online 20120111 Pt 2

In the title compound, (C(14)H(12)NO)(2)[ZnCl(4)], the benzo[h]quinolinium groups are approximately planar, with maximum deviations of 0.049 (8) and 0.056 (9) Å. The meth-oxy groups are stabilized by intra-molecular N-H⋯O hydrogen bonds. The structure also exhibits weak inter-molecular N-H⋯Cl hydrogen bonds between the cations and anions. π-π inter-actions are present between the pyridinium and benzene rings [centroid-centroid distances = 3.640 (4), 3.728 (5) and 3.628 (5) Å]. ...[more]

PMID: 22346816

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