Ontology highlight
ABSTRACT:
SUBMITTER: Ha K
PROVIDER: S-EPMC3274878 | biostudies-other | 2012 Feb
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20120114 Pt 2
The Pd(II) ion in the title complex, [Pd(NCS)(2)(C(14)H(10)N(4))], is four-coordinated in a distorted square-planar environment by the two pyridine N atoms of the chelating 2,3-di-2-pyridyl-pyrazine (dpp) ligand and two S atoms from two thio-cyanate anions. The pyridine rings are considerably inclined to the least-squares plane of the PdS(2)N(2) unit [maximum deviation = 0.027 (1) Å], making dihedral angles of 70.3 (2) and 69.2 (1)°. The pyrazine ring is almost perpendicular to the PdS(2)N(2) pl ...[more]