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Hexaaqua-magnesium(II) bis-{5-[3-(1H-tetra-zol-5-yl)phen-yl]tetra-zolide} tetra-hydrate.

ABSTRACT: The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(8)H(5)N(8))(2)·4H(2)O, contains one half of the centrosymmetric dication, one anion and two water mol-ecules. The Mg(II) ion is coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. In the anion, the two five-membered heterocycles are twisted from the central benzene ring by 4.34?(11) and 3.20?(10)°. In the crystal, O-H?N, O-H?O and N-H?O hydrogen bonds generate a three-dimensional network.

SUBMITTER: Qiao CF

PROVIDER: S-EPMC3274901 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Hexaaqua-magnesium(II) bis-{5-[3-(1H-tetra-zol-5-yl)phen-yl]tetra-zolide} tetra-hydrate.

Qiao Cheng-Fang CF Zhou Chun-Sheng CS

Acta crystallographica. Section E, Structure reports online 20120118 Pt 2

The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(8)H(5)N(8))(2)·4H(2)O, contains one half of the centrosymmetric dication, one anion and two water mol-ecules. The Mg(II) ion is coordinated by six water mol-ecules in a slightly distorted octa-hedral geometry. In the anion, the two five-membered heterocycles are twisted from the central benzene ring by 4.34 (11) and 3.20 (10)°. In the crystal, O-H⋯N, O-H⋯O and N-H⋯O hydrogen bonds generate a three-dimensional network. ...[more]

PMID: 22346848

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