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Poly[piperazine-1,4-diium [?(4)-chlorido-?(3)-chlorido-tri-?(2)-chlorido-chloridodicadmate(II)] monohydrate].

ABSTRACT: In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2-) anion and a water mol-ecule. The coordination geometries of the two Cd(2+) cations are distorted octa-hedral. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O-H?Cl hydrogen bonds involving the water mol-ecules, forming layers at z = n/2. The crystal packing is further stabilized by inter-molecular N-H?Cl and N-H?O hydrogen bonds, one of which is bifurcated.

SUBMITTER: Adib M 

PROVIDER: S-EPMC3274903 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Poly[piperazine-1,4-diium [μ(4)-chlorido-μ(3)-chlorido-tri-μ(2)-chlorido-chloridodicadmate(II)] monohydrate].

Adib Marwa M   El Glaoui Meher M   Pereira da Silva Pedro Sidonio PS   Ramos Silva Manuela M   Ben Nasr Cherif C  

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

In the title compound, {(C(5)H(14)N(2))[Cd(2)Cl(6)]·H(2)O}(n), the asymmetric unit contains one piperazinediium cation, one [Cd(2)Cl(6)](2-) anion and a water mol-ecule. The coordination geometries of the two Cd(2+) cations are distorted octa-hedral. Adjacent Cd(II) atoms are inter-connected alternately by paired chloride bridges, generating polymeric chains parallel to [010]. Neighbouring chains are connected by O-H⋯Cl hydrogen bonds involving the water mol-ecules, forming layers at z = n/2. Th  ...[more]

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