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All-yl(ferrocenylmeth-yl)dimethyl-ammonium perchlorate.

ABSTRACT: The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all-yl(ferro-cenyl-meth-yl)dimethyl-ammonium cations and two ClO(4) (-) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617?(6):0.383?(6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.645?(1)/1.657?(1) and 1.644?(1)/1.647?(1)?Å. The dihedral angles between the two Cp rings are 2.49?(3) and 1.45?(4)° in the two ferrocenyl groups of the cations.

SUBMITTER: Wang YC

PROVIDER: S-EPMC3274906 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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All-yl(ferrocenylmeth-yl)dimethyl-ammonium perchlorate.

Wang Ying-Chun YC

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all-yl(ferro-cenyl-meth-yl)dimethyl-ammonium cations and two ClO(4) (-) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617 (6):0.383 (6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.645 (1)/1.657 (1) and 1.644 (1)/1.647 (1) Å. The dihedral angles between the two Cp rings are ...[more]

PMID: 22346853

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