All-yl(ferrocenylmeth-yl)dimethyl-ammonium perchlorate.

ABSTRACT: The asymmetric unit of the title complex, [Fe(C(5)H(5))(C(11)H(17)N)]ClO(4), contains two independent all-yl(ferro-cenyl-meth-yl)dimethyl-ammonium cations and two ClO(4) (-) anions. The anions are disordered each over two sets of sites, with an occupancy ratio of 0.617?(6):0.383?(6). The distances from the Fe atoms to the centroids of the unsubstituted and substituted cyclo-penta-dienyl (Cp) rings are 1.645?(1)/1.657?(1) and 1.644?(1)/1.647?(1)?Å. The dihedral angles between the two Cp rings are 2.49?(3) and 1.45?(4)° in the two ferrocenyl groups of the cations.

SUBMITTER: Wang YC 

PROVIDER: S-EPMC3274906 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other