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Catena-Poly[4-methyl-morpholin-4-ium [[dichloridobismuth(III)]-di-?-chlorido]].

ABSTRACT: The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl-morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octa-hedral geometry about each Bi(III) atom. Bifurcated N-H?Cl hydrogen bonds link the cations to the anionic chains.

SUBMITTER: Wang YC

PROVIDER: S-EPMC3274907 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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catena-Poly[4-methyl-morpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]].

Wang Ying-Chun YC

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

The asymmetric unit of the title complex, {(C(5)H(12)NO)[BiCl(4)]}(n), contains two bridging and two cis non-bridging chloride ligands coordinated to a central Bi(III) atom, and one 4-methyl-morpholin-4-ium cation. The Bi(III) atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octa-hedral geometry about each Bi(III) atom. Bifurcated N-H⋯Cl hydrogen bonds link the cations to the anionic chains. ...[more]

PMID: 22346854

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