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Catena-Poly[[(isoquinoline-?N)(triphenylphospane-?P)copper(I)]-?-thio-cyanato-?N:S].

ABSTRACT: In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetra-hedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenyl-phospane ligand, and one N and one S atom from two thio-cyanate anions. The thio-cyanide anions bridge the Cu(I) atoms into a chain along [100]. ?-? inter-actions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722?(3)?Å].

SUBMITTER: Li JB

PROVIDER: S-EPMC3297240 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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catena-Poly[[(isoquinoline-κN)(triphenylphospane-κP)copper(I)]-μ-thio-cyanato-κN:S].

Li Jian-Bao JB Zhou Li-Li LL Wu Man-Hua MH Jin Qiong-Hua QH Zhang Cun-Lin CL

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetra-hedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenyl-phospane ligand, and one N and one S atom from two thio-cyanate anions. The thio-cyanide anions bridge the Cu(I) atoms into a chain along [100]. π-π inter-actions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722 (3) Å]. ...[more]

PMID: 22412430

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