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{3,3'-Bis[(anthracen-9-yl)meth-yl]-1,1'-[(ethane-1,2-diyldi-oxy)bis-(ethane-1,2-di-yl)]bis-(imidazol-2-yl-idene)}mercury(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.

ABSTRACT: In the title compound, [Hg(C(42)H(38)N(4)O(2))](PF(6))(2)·2CH(3)CN, the Hg(II) cation lies on a twofold axis which is also the inter-nal symmetry element of the complete cationic complex. The Hg(II) cation is coordinated by two symmetry-related C(carbene) atoms [Hg-C = 2.058?(9)?Å] in a nearly linear geometry, with a C-Hg-C angle of 175.8?(5)°. There are weak inter-molecular C-H?F inter-actions in the crystal packing between an F atom of a hexa-fluoridophosphate anion and a -CH(2)- group of the bis-N-heterocyclic carbene ligand.

SUBMITTER: Wang JW

PROVIDER: S-EPMC3297254 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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{3,3'-Bis[(anthracen-9-yl)meth-yl]-1,1'-[(ethane-1,2-diyldi-oxy)bis-(ethane-1,2-di-yl)]bis-(imidazol-2-yl-idene)}mercury(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.

Wang Jun-Wen JW Guo Yue Y Dong Gui-Ying GY Gu Yu Y Bai Di-Si DS

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the title compound, [Hg(C(42)H(38)N(4)O(2))](PF(6))(2)·2CH(3)CN, the Hg(II) cation lies on a twofold axis which is also the inter-nal symmetry element of the complete cationic complex. The Hg(II) cation is coordinated by two symmetry-related C(carbene) atoms [Hg-C = 2.058 (9) Å] in a nearly linear geometry, with a C-Hg-C angle of 175.8 (5)°. There are weak inter-molecular C-H⋯F inter-actions in the crystal packing between an F atom of a hexa-fluoridophosphate anion and a -CH(2)- group of the ...[more]

PMID: 22412444

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