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Methyl (Z)-2-[(4-bromo-2-formyl-phen-oxy)meth-yl]-3-(4-methyl-phen-yl)acrylate.

ABSTRACT: In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9?(2)°. The mol-ecular structure is stabilized by an intra-molecular C-H?O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C-H?O hydrogen bonds, which generate two centrosymmetic ring systems with R(2) (2)(18) and R(2) (2)(14) graph-set motifs. The crystal packing is further stabilized by inter-molecular ?-? inter-actions [centroid-centroid distance = 3.984?(2)?Å].

SUBMITTER: Vijayakumar S

PROVIDER: S-EPMC3297846 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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Methyl (Z)-2-[(4-bromo-2-formyl-phen-oxy)meth-yl]-3-(4-methyl-phen-yl)acrylate.

Vijayakumar S S Murugavel S S Kannan D D Bakthadoss M M

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.9 (2)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯O hydrogen bond, which generates an S(7) ring motif. The crystal packing is stabilized by C-H⋯O hydrogen bonds, which generate two centrosymmetic ring systems with R(2) (2)(18) and R(2) (2)(14) graph-set motifs. The crystal packing is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.984 (2) ...[more]

PMID: 22412649

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