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(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-cyclo-hexyl-hydrazine-carbothio-amide.

ABSTRACT: The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio-amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol-ecules are paired through N-H?O and O-H?S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are inter-connected through N-H?S hydrogen bonds to generate polymeric chains. The structure also features C-H?? interactions. An intra-molecular O-H?O bond is also present.

SUBMITTER: Jacob JM

PROVIDER: S-EPMC3297895 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-cyclo-hexyl-hydrazine-carbothio-amide.

Jacob Jinsa Mary JM Kurup M R Prathapachandra MR

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

The title compound, C(15)H(20)BrN(3)O(2)S, crystallizes in the thio-amide form and adopts an E,E conformation with respect to the azomethine and hydrazinic bonds, respectively. The mol-ecules are paired through N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of centrosymmetric dimers in the crystal. These dimers are stacked along the a axis and are inter-connected through N-H⋯S hydrogen bonds to generate polymeric chains. The structure also features C-H⋯π interactions. An intra-molecula ...[more]

PMID: 22412698

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2-Cyclo-hexyl-idene-N-methyl-hydrazine-carbothio-amide.

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