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Induction of pH sensitivity on the fluorescence lifetime of quantum dots by NIR fluorescent dyes.

ABSTRACT: Modulation of the fluorescence lifetime (FLT) of CdTeSe/ZnS quantum dots (QDs) by near-IR (NIR) organic chromophores represents a new strategy for generating reproducible pH-sensing nanomaterials. The hybrid construct transfers the pH sensitivity of photolabile NIR cyanine dyes to highly emissive and long-lifetime pH-insensitive QDs, thereby inducing a reproducible FLT change from 29 ns at pH >7 to 12 ns at pH <5. This approach provides an unparalleled large dynamic FLT range for pH sensing at NIR wavelengths.

SUBMITTER: Tang R 

PROVIDER: S-EPMC3303939 | biostudies-other | 2012 Mar

REPOSITORIES: biostudies-other

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Induction of pH sensitivity on the fluorescence lifetime of quantum dots by NIR fluorescent dyes.

Tang Rui R   Lee Hyeran H   Achilefu Samuel S  

Journal of the American Chemical Society 20120228 10

Modulation of the fluorescence lifetime (FLT) of CdTeSe/ZnS quantum dots (QDs) by near-IR (NIR) organic chromophores represents a new strategy for generating reproducible pH-sensing nanomaterials. The hybrid construct transfers the pH sensitivity of photolabile NIR cyanine dyes to highly emissive and long-lifetime pH-insensitive QDs, thereby inducing a reproducible FLT change from 29 ns at pH >7 to 12 ns at pH <5. This approach provides an unparalleled large dynamic FLT range for pH sensing at N  ...[more]