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Dichlorido[2-(phenyl-imino-meth-yl)quinoline-N,N']palladium(II).

ABSTRACT: In the title complex, [PdCl(2)(C(16)H(12)N(2))], the Pd(II) ion is coordinated by two N atoms [Pd-N 2.039?(2), 2.073?(2)?Å] from a bidentate ligand and two chloride anions [Pd-Cl 2.2655?(7), 2.2991?(7)?Å] in a distorted square-planar geometry. In the crystal, ?-? inter-actions between the six-membered rings of the quinoline fragments [centroid-centroid distances = 3.815?(5), 3.824?(5)?Å] link two mol-ecules into centrosymmetric dimers.

SUBMITTER: Motswainyana WM

PROVIDER: S-EPMC3343797 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Dichlorido[2-(phenyl-imino-meth-yl)quinoline-N,N']palladium(II).

Motswainyana William M WM Onani Martin O MO Madiehe Abram M AM

Acta crystallographica. Section E, Structure reports online 20120307 Pt 4

In the title complex, [PdCl(2)(C(16)H(12)N(2))], the Pd(II) ion is coordinated by two N atoms [Pd-N 2.039 (2), 2.073 (2) Å] from a bidentate ligand and two chloride anions [Pd-Cl 2.2655 (7), 2.2991 (7) Å] in a distorted square-planar geometry. In the crystal, π-π inter-actions between the six-membered rings of the quinoline fragments [centroid-centroid distances = 3.815 (5), 3.824 (5) Å] link two mol-ecules into centrosymmetric dimers. ...[more]

PMID: 22589771

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