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Bis{S-benzyl 3-[(phen-yl)(pyridin-2-yl)methyl-idene]dithio-carbazato}zinc acetonitrile monosolvate.

ABSTRACT: In the title compound, [Zn(C(20)H(16)N(3)S(2))(2)]·CH(3)CN, two different Schiff base moieties coordinate to the central Zn(II) ion as tridentate N,N',S-chelating ligands, creating a distorted octa-hedral environment [the smallest angle being 73.24?(6)° and the widest angle being 155.73?(7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65?(5)°. The crystal packing is consolidated by weak C-H?N hydrogen-bonding inter-actions.

SUBMITTER: Ravoof TB

PROVIDER: S-EPMC3343804 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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