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3,5-Dimethyl-1-(4-nitro-benz-yl)pyridinium bis-(benzene-1,2-dithiol-ato-?(2)S,S')nickelate(III).

ABSTRACT: The asymmetric unit of the title compound, (C(14)H(15)N(2)O(2))[Ni(C(6)H(4)S(2))(2)], contains one cation and two halves of two centrosymmetric crystallographically independent anions. In the anions, the Ni(III) atoms are coordinated by four S atoms in a distorted square-planar geometry. In the cation, the dihedral angle between the pyridine and benzene rings is 88.66?(17)°. In the crystal, anions and cations inter-act through C-H?S and C-H?O hydrogen bonds.

SUBMITTER: Liu GX 

PROVIDER: S-EPMC3343816 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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3,5-Dimethyl-1-(4-nitro-benz-yl)pyridinium bis-(benzene-1,2-dithiol-ato-κ(2)S,S')nickelate(III).

Liu Guang-Xiang GX  

Acta crystallographica. Section E, Structure reports online 20120314 Pt 4

The asymmetric unit of the title compound, (C(14)H(15)N(2)O(2))[Ni(C(6)H(4)S(2))(2)], contains one cation and two halves of two centrosymmetric crystallographically independent anions. In the anions, the Ni(III) atoms are coordinated by four S atoms in a distorted square-planar geometry. In the cation, the dihedral angle between the pyridine and benzene rings is 88.66 (17)°. In the crystal, anions and cations inter-act through C-H⋯S and C-H⋯O hydrogen bonds. ...[more]

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