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Cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-?N(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

ABSTRACT: In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four water mol-ecules, together with two water mol-ecules of solvation. The Mn(2+) ion lies on a twofold rotation axis and has a slightly distorted octa-hedral geometry. The mol-ecules are connected by O-H?N and O-H?O hydrogen bonds involving both coordinated and solvent water mol-ecules, generating a three-dimensional structure. Two C atoms of the imidazole ring of the ligand are each disordered over two sites with occupancy factors of 0.75 and 0.25.

SUBMITTER: Wang X

PROVIDER: S-EPMC3343820 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-κN(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

Wang Xin X Yan Shi-Wei SW Chang Suo-Cheng SC Liang Yan-Chen YC Zhang Fu-Tian FT

Acta crystallographica. Section E, Structure reports online 20120314 Pt 4

In the title compound, [Mn(C(10)H(7)N(6))(2)(H(2)O)(4)]·2H(2)O, the complex unit comprises an Mn(2+) ion, coordinated by two imidazole N atoms from cis-related monodentate 5-[4-(imidazol-1-yl)phen-yl]tetra-zolide ligands and four water mol-ecules, together with two water mol-ecules of solvation. The Mn(2+) ion lies on a twofold rotation axis and has a slightly distorted octa-hedral geometry. The mol-ecules are connected by O-H⋯N and O-H⋯O hydrogen bonds involving both coordinated and solvent wat ...[more]

PMID: 22589794

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cis-Tetra-aqua-bis-{5-[4-(1H-imidazol-1-yl-?N(3))phen-yl]tetra-zolido}manganese(II) dihydrate.

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