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Bis(1H-benzimidazole-?N(3))bis-[2-(naphthalen-1-yl)acetato-?(2)O,O']nickel(II) monohydrate.

ABSTRACT: In the title compound, [Ni(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, The Ni(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted NiN(2)O(4) octa-hedral geometry. The asymmetric unit consists of a nickel(II) ion, one 2-(naphthalen-1-yl)acetate anion, a neutral benzotriazole ligand and one half of a lattice water mol-ecule. The crystal packing is stabilized by O-H?O and N-H?O hydrogen bonds. The title compound is isotypic with its Cd(II) analogue.

SUBMITTER: Yin FJ

PROVIDER: S-EPMC3343822 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Bis(1H-benzimidazole-κN(3))bis-[2-(naphthalen-1-yl)acetato-κ(2)O,O']nickel(II) monohydrate.

Yin Fu-Jun FJ Han Li-Jun LJ Hong Zhao Z Xu Xing-You XY Ren Li L

Acta crystallographica. Section E, Structure reports online 20120314 Pt 4

In the title compound, [Ni(C(12)H(9)O(2))(2)(C(7)H(6)N(2))(2)]·H(2)O, The Ni(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted NiN(2)O(4) octa-hedral geometry. The asymmetric unit consists of a nickel(II) ion, one 2-(naphthalen-1-yl)acetate anion, a neutral benzotriazole ligand and one half of a lattice water mol-ecule. The crystal packing is stabilized by O-H⋯O and N-H⋯O hydrogen bonds. The title compound is isotypic with its Cd(II) analogue. ...[more]

PMID: 22589796

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