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Bis(azido-?N)bis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-?(2)N(1),N(6)]manganese(II).

ABSTRACT: In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa-hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75?(5)°. The mononuclear mol-ecules are alternatively linked into layers parallel to the ac plane via N-H?N hydrogen bonds. Adjacent layers are connected into a three-dimensional supra-molecular framework by futher N-H?N hydrogen-bonding inter-actions.

SUBMITTER: Wang KM

PROVIDER: S-EPMC3343829 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Bis(azido-κN)bis-[6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine-κ(2)N(1),N(6)]manganese(II).

Wang Kun-Miao KM Liu Zhi-Hua ZH Zheng Qi Q Liu Chun-Bo CB Miao Ming-Ming MM

Acta crystallographica. Section E, Structure reports online 20120317 Pt 4

In the title complex, [Mn(N(3))(2)(C(8)H(8)N(6))(2)], the complete molecule is generated by the application of twofold symmetry, and is in a distorted octa-hedral environment, coordinated by four N atoms of two bidentate 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands and two N atoms from two azide anions. The two chelated 6-(pyridin-2-yl)-1,3,5-triazine-2,4-diamine ligands form a dihedral angle 74.75 (5)°. The mononuclear mol-ecules are alternatively linked into layers parallel to the ac pl ...[more]

PMID: 22589803

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