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Bis[2-(diphenyl-phosphanyl-?P)benzaldehyde]-iodidogold(I).

ABSTRACT: In the title compound, [AuI(C(19)H(15)OP)(2)], the complete mol-ecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal-planar geometry within an IP(2) donor set with the greatest distortion seen in the P-Au-P angle [128.49?(3) °]. Close intra-molecular Au?O inter-actions [3.172?(3)?Å] are observed. No specific inter-molecular inter-actions are noted in the crystal packing.

SUBMITTER: Williams ML

PROVIDER: S-EPMC3343862 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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Bis[2-(diphenyl-phosphanyl-κP)benzaldehyde]-iodidogold(I).

Williams Michael L ML Dunstan Samuel P C SP Healy Peter C PC Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20120324 Pt 4

In the title compound, [AuI(C(19)H(15)OP)(2)], the complete mol-ecule is generated by the application of twofold symmetry. The Au(I) atom is in a trigonal-planar geometry within an IP(2) donor set with the greatest distortion seen in the P-Au-P angle [128.49 (3) °]. Close intra-molecular Au⋯O inter-actions [3.172 (3) Å] are observed. No specific inter-molecular inter-actions are noted in the crystal packing. ...[more]

PMID: 22589836

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