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Cis-Dichloridobis(quinoline-?N)-platinum(II) nitro-methane monosolvate.

ABSTRACT: In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(-) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042?(6) and 0.018?(7)?Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024?(3)?Å], making a dihedral angle of 89.6?(1)°, whereas the other is slightly inclined to the central plane with a dihedral angle of 74.1?(1)°. The dihedral angle between the quinoline ligands is 88.3?(2)°. In the crystal, each solvent mol-ecule is linked to the metal complex by weak inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Ha K

PROVIDER: S-EPMC3343880 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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cis-Dichloridobis(quinoline-κN)-platinum(II) nitro-methane monosolvate.

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20120328 Pt 4

In the title compound, [PtCl(2)(C(9)H(7)N)(2)]·CH(3)NO(2), the Pt(II) cation is four-coordinated in an essentially square-planar environment by two N atoms from two quinoline ligands and two Cl(-) anions. One of the nearly planar quinoline ligands [maximum deviations = 0.042 (6) and 0.018 (7) Å] is almost perpendicular to the PtCl(2)N(2) unit [maximum deviation = 0.024 (3) Å], making a dihedral angle of 89.6 (1)°, whereas the other is slightly inclined to the central plane with a dihedral angle ...[more]

PMID: 22589848

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