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Trans-Dichloridobis(triphenyl-phosphane-?P)palladium(II) benzene hemisolvate.

ABSTRACT: The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024?Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ?). Acta Cryst. C39, 1015-1017].

SUBMITTER: Meyer-Wegner F 

PROVIDER: S-EPMC3343891 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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trans-Dichloridobis(triphenyl-phosphane-κP)palladium(II) benzene hemisolvate.

Meyer-Wegner Frank F   Lerner Hans-Wolfram HW   Sinke Tanja T   Bolte Michael M  

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4

The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-dichloro-benzene sesquisolvate [Kitano et al. (1983 ▶). Acta Cryst. C39, 1015-1017]. ...[more]