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{5,5'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}palladium(II).

ABSTRACT: In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol-ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd-O and Pd-N distances are 1.9932?(6) and 2.0029?(7)?Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21?(4)°. In the crystal, C-H?O hydrogen bonds link the mol-ecules into layers parallel to the ab plane. These planes are further connected by C-H?O inter-actions, forming a three-dimensional network.

SUBMITTER: Che Soh SK

PROVIDER: S-EPMC3343897 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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{5,5'-Dimeth-oxy-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]diphenolato}palladium(II).

Che Soh Siti Kamilah SK Shamsuddin Mustaffa M Rosli Mohd Mustaqim MM Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4

In the title compound, [Pd(C(21)H(24)N(2)O(4))], the complete mol-ecule is generated by crystallographic mirror symmetry with the Pd and three C atoms lying on the mirror plane. The Pd-O and Pd-N distances are 1.9932 (6) and 2.0029 (7) Å, respectively. The dihedral angle between two benzene rings of the ligand is 79.21 (4)°. In the crystal, C-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the ab plane. These planes are further connected by C-H⋯O inter-actions, forming a three-dim ...[more]

PMID: 22589865

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