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4-Bromo-N-(4-meth-oxy-2-nitro-phen-yl)benzamide.

ABSTRACT: In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4?(2) and 20.5?(2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90?(8)°. The nitro and meth-oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. deviation for the 11 non-H atoms being 0.0265?(1)?Å. An intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked into [2-10] chains by weak C-H?O and C-H?Br inter-actions, which form an R(2) (2)(8) motif between pairs of mol-ecules in the chain. A Br?O [3.2018?(12)?Å] short contact also occurs.

SUBMITTER: Sripet W

PROVIDER: S-EPMC3344164 | biostudies-other | 2012 Apr

REPOSITORIES: biostudies-other

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4-Bromo-N-(4-meth-oxy-2-nitro-phen-yl)benzamide.

Sripet Weerawat W Chantrapromma Suchada S Ruanwas Pumsak P Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120331 Pt 4

In the title compound, C(14)H(11)BrN(2)O(4), the amide segment makes dihedral angles of 23.4 (2) and 20.5 (2)° with the benzene rings, while the dihedral angle between the bezene rings is 2.90 (8)°. The nitro and meth-oxy groups are almost coplanar with their bound benzene ring, with the r.m.s. deviation for the 11 non-H atoms being 0.0265 (1) Å. An intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol-ecules are linked into [2-10] chains by weak C-H⋯O and C-H⋯Br ...[more]

PMID: 22606167

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