Unknown

Dataset Information

0

Poly[[diaqua-[?(2)-3-carb-oxy-5-(pyridine-4-carboxamido)-benzoato][?(4)-5-(pyridine-4-carboxamido)-isophthalato]cerium(III)] monohydrate].


ABSTRACT: In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O-H?N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol-ecules in a distorted square-anti-prismatic arrangement. Extensive O-H?O and O-H?N hydrogen bonding occurs in the crystal structure.

SUBMITTER: Deng YF 

PROVIDER: S-EPMC3344292 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

altmetric image

Publications

Poly[[diaqua-[μ(2)-3-carb-oxy-5-(pyridine-4-carboxamido)-benzoato][μ(4)-5-(pyridine-4-carboxamido)-isophthalato]cerium(III)] monohydrate].

Deng Yi-Fang YF   Nie Xue X  

Acta crystallographica. Section E, Structure reports online 20120404 Pt 5


In the title compound, {[Ce(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))(H(2)O)(2)]·H(2)O}(n), three carboxyl groups of two independent isophthalate anions are deprotonated and they bridge the Ce(III) cations, forming a two-dimensional polymeric structure parallel to (001); another carboxyl group is not deprotonated and links with the adjacent pyridine ring via an O-H⋯N hydrogen bond. The Ce(III) cation is coordinated by six O atoms from carboxyl groups and two O atoms from coordinated water mol-ecules  ...[more]

Similar Datasets

| S-EPMC3414142 | biostudies-literature
| S-EPMC3099755 | biostudies-literature
| S-EPMC3201412 | biostudies-literature
| S-EPMC3200962 | biostudies-literature
| S-EPMC3772404 | biostudies-literature
| S-EPMC3051994 | biostudies-literature
| S-EPMC3246915 | biostudies-literature
| S-EPMC3246991 | biostudies-literature
| S-EPMC2961213 | biostudies-literature
| S-EPMC2970155 | biostudies-literature