Unknown

Dataset Information

0

[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-?(2)P,P'](?(5)-cyclo-penta-dien-yl)(dicyanamido-?N)ruthenium(II) dichloro-methane monosolvate.

ABSTRACT: The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an ?(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [120.8?(6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2?(9)°; Zhang et al. (2003 ?). Inorg. Chem.42, 633-640] due to steric hindrance between the two {Cp(PPh(3))(2)Ru} building blocks. Disorder was found in the dichloro-methane solvent mol-ecule, which was refined as disordered over two positions, with a site-occupancy ratio of 0.53:0.47?(2).

SUBMITTER: Gao L 

PROVIDER: S-EPMC3344313 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

[1,1'-Bis(diphenyl-phosphan-yl)ferrocene-κ(2)P,P'](η(5)-cyclo-penta-dien-yl)(dicyanamido-κN)ruthenium(II) dichloro-methane monosolvate.

Gao Libin L  

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5

The title compound, [FeRu(C(5)H(5))(C(2)N(3))(C(17)H(14)P)(2)], was obtained by reaction of Cp(dppf)RuCl [dppf = 1,1'-bis-(diphenyl-phosphan-yl)ferrocene] with sodium dicyanamide in dichloro-methane. The Ru(II) atom is capped by an η(5)-cyclo-penta-dienyl (Cp) ring, a chelating dppf and a terminal C(2)N(3) unit, giving three-legged piano-stool geometry. The C-N-C angle of the N(CN)(2) ligand [120.8 (6)°] is significantly smaller than that in the corresponding diruthenium complex [127.2 (9)°; Zha  ...[more]

Similar Datasets

Unknown [1,1'-Bis(diphenyl-phosphan-yl)ferrocene-?P,P']dichloridocadmium(II) dichloro-methane disolvate.
| S-EPMC3011616 | biostudies-literature
Unknown (?-Isopropyl N-phenyl-carbamate)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate acetone monosolvate.
| S-EPMC3200656 | biostudies-literature
Unknown 1,1'-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]ferrocene.
| S-EPMC3393188 | biostudies-literature
Unknown [1,1'-Bis(di-phenyl-phosphan-yl)cobalto-cenium-?(2) P,P'](?(5)-cyclo-penta-dien-yl){2-[4-(4-ethynylphen-yl)phen-yl]ethynyl-?C}ruthenium(II) hexa-fluorido-phosphate.
| S-EPMC3884261 | biostudies-literature
Unknown (?-Benzophenone)(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) tetra-phenyl-borate.
| S-EPMC2971317 | biostudies-literature
Unknown (?-Penta-methyl-cyclo-penta-dien-yl)(?-toluene)-ruthenium(II) hexa-fluorido-phosphate.
| S-EPMC2983397 | biostudies-literature
Unknown [1,1'-Bis(diphenyl-phosphan-yl)cobalto-cenium]carbonyl-chloridohydrido(triphenyl-phosphane)ruthenium(II) hexa-fluoridophosphate dichloro-methane disolvate.
| S-EPMC3238603 | biostudies-literature
Unknown rac-cis,cis-Dicarbonyl-dichlorido{1-[2-(diphenyl-phosphan-yl)benz-yl]-3-mesityl-imidazol-2-yl-idene}ruthenium(II) dichloro-methane monosolvate.
| S-EPMC3414164 | biostudies-literature
Unknown (?-Cyclo-penta-dien-yl)(?-mesitylamine)ruthenium(II) hexa-fluorido-phosphate.
| S-EPMC2969571 | biostudies-literature
Unknown [1,1'-Bis(dicyclo-hexyl-phosphino)cobalto-cenium-?P,P']chlorido(?-cyclo-penta-dien-yl)ruthenium(II) hexa-fluorido-phosphate.
| S-EPMC2979948 | biostudies-literature