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Catena-Poly[[[penta-aqua-cerium(III)]-?-pyridine-2,4,6-tricarboxyl-ato-?(4)N,O(2),O(6):O(6')] tetra-hydrate].


ABSTRACT: The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O'-chelated by the carboxyl-ate trianion and is coordinated by five water mol-ecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water mol-ecules inter-act with each other and with the carboxyl O atoms by O-H?O hydrogen bonds, generating a three-dimensional network.

SUBMITTER: Sharif S 

PROVIDER: S-EPMC3344357 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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catena-Poly[[[penta-aqua-cerium(III)]-μ-pyridine-2,4,6-tricarboxyl-ato-κ(4)N,O(2),O(6):O(6')] tetra-hydrate].

Sharif Shahzad S   Khan Islam Ullah IU   Zaheer Samia S   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5


The Ce(III) atom in the title compound, {[Ce(C(8)H(2)NO(6))(H(2)O)(5)]·4H(2)O}(n), is N,O,O'-chelated by the carboxyl-ate trianion and is coordinated by five water mol-ecules; a carboxyl O atom from an adjacent trianion bridges the Ce(III) atom, resulting in a chain running along the a axis. The nine atoms surrounding the metal atom comprise a tricapped trigonal-prismatic polyhedron. The coordinated and lattice water mol-ecules inter-act with each other and with the carboxyl O atoms by O-H⋯O hyd  ...[more]

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