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Bis(3-methyl-anilinium) hexa-chlorido-stannate(IV) dihydrate.

ABSTRACT: In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methyl-anilinium cation is also situated on a mirror plane. The water mol-ecule is located on a twofold rotation axis. The H atoms of the methyl and ammonium groups and the solvent water mol-ecule are disordered by symmetry. In the crystal, N-H?Cl, O-H?Cl and N-H?O hydrogen bonds connect the organic cations, the inorganic octahedrally shaped anions and the water mol-ecules.

SUBMITTER: Liu ML

PROVIDER: S-EPMC3344401 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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Bis(3-methyl-anilinium) hexa-chlorido-stannate(IV) dihydrate.

Liu Ming-Liang ML

Acta crystallographica. Section E, Structure reports online 20120428 Pt 5

In the title compound, (C(7)H(10)N)(2)[SnCl(6)]·2H(2)O, the Sn(IV) atom lies on a site with symmetry 2/m. One of the Cl atoms lies on a mirror plane and the 3-methyl-anilinium cation is also situated on a mirror plane. The water mol-ecule is located on a twofold rotation axis. The H atoms of the methyl and ammonium groups and the solvent water mol-ecule are disordered by symmetry. In the crystal, N-H⋯Cl, O-H⋯Cl and N-H⋯O hydrogen bonds connect the organic cations, the inorganic octahedrally shap ...[more]

PMID: 22590163

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