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N-(2-{[7-(2-Anilinoeth-oxy)-3,6-dibromo-naphthalen-2-yl]-oxy}eth-yl)aniline.


ABSTRACT: In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two -CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17?(17) and 51.4?(2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N-C-C-O torsion angles = 68.6?(4) and 60.5?(4)°]. In the crystal, one of the N-H groups forms bifurcated N-H?(Br,O) hydrogen bonds, which link the mol-ecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C-H?? inter-actions into sheets parallel to (110).

SUBMITTER: Zong QS 

PROVIDER: S-EPMC3344487 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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N-(2-{[7-(2-Anilinoeth-oxy)-3,6-dibromo-naphthalen-2-yl]-oxy}eth-yl)aniline.

Zong Qian-Shou QS   Wu Jian-Yi JY  

Acta crystallographica. Section E, Structure reports online 20120413 Pt 5


In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two -CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N-C-C-O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N-H groups forms bifurcated N-H⋯(Br,O) hy  ...[more]

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