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2-Chloro-N-(2,6-dimethyl-phen-yl)benzamide.

ABSTRACT: In the title compound, C(15)H(14)ClNO, the dihedral angle between the benzoyl and the aniline rings is 3.30?(18)°. In the crystal, N-H?O hydrogen bonds link the mol-ecules into chains running along the a axis.

SUBMITTER: Rodrigues VZ

PROVIDER: S-EPMC3344534 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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2-Chloro-N-(2,6-dimethyl-phen-yl)benzamide.

Rodrigues Vinola Z VZ Gowda B Thimme BT Sivý Július J Vrábel Viktor V Kožíšek Jozef J

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the title compound, C(15)H(14)ClNO, the dihedral angle between the benzoyl and the aniline rings is 3.30 (18)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains running along the a axis. ...[more]

PMID: 22590296

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4-Chloro-N-(2,6-dimethyl-phen-yl)benzamide.

Project description:The conformations of the N-H and C=O bonds in the structure of the title compound (N26DMP4CBA), C(15)H(14)ClNO, are anti to each other, similar to that observed in N-phenyl-benzamide, N-(3,4-dimethyl-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benzamide and other benzanilides. There are three mol-ecules in the asymmetric unit of N26DMP4CBA. The central amide group is tilted with respect to the benzoyl ring by 45.2?(1)° in mol-ecule 1, 21.2?(2)° in mol-ecule 2 and 14.9?(2)° in mol-ecule 3. The dihedral angles between the benzoyl and aniline rings are 39.9?(1), 51.0?(1) and 86.3?(3)° in mol-ecules 1, 2 and 3, respectively. Inter-molecular N-H?O hydrogen bonds link the mol-ecules into infinite chains running along the [101] direction. One xylyl group is disordered over two positions; the site occupancy factors are ca 0.6 and 0.4.

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N-(2,6-Dimethyl-phen-yl)benzamide.

Project description:The title compound, C(15)H(15)NO, crystallizes with two mol-ecules in the asymmetric unit. The H-N-C=O units are in a trans conformation, similar to that observed in N-(3,4-dimethyl-phen-yl)benzamide, N-(2,6-dichloro-phen-yl)benz-amide and other benzanilides. The central -NHCO- bridging unit is tilted at angles of 17.1?(3) and 16.4?(3)° to the benzoyl ring in the two mol-ecules. The two rings (benzoyl and aniline) are almost orthogonal with respect to each other, making dihedral angles of 86.3?(1) and 86.0?(1)° in the two mol-ecules. N-H?O hydrogen bonds link mol-ecules into infinite chains running along the c axis.

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2-Chloro-N-(2,6-dichloro-phen-yl)benzamide.

Project description:In the structure of the title compound (N26DCP2CBA), C(13)H(8)Cl(3)NO, the conformations of N-H and C=O bonds in the amide group are trans to each other, similar to that observed in N-(2,6-dichloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, 2-chloro-N-(2-chloro-phen-yl)benzamide and 2-chloro-N-(2,3-dichloro-phen-yl)benzamide with similar bond parameters. Furthermore, the position of the amide O atom is syn to the ortho-chloro group in the benzoyl ring. The amide group makes a dihedral angle of 59.8?(1)° with the benzoyl ring, while the benzoyl and aniline rings make a dihedral angle of 8.1?(2)°. The mol-ecules are linked by N-H?O hydrogen bonds into infinite chains running along the b axis.

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N-(2,6-Dimethyl-phen-yl)-2-methyl-benzamide.

Project description:In the title mol-ecule, C(16)H(17)NO, the N-H and C=O groups are in the anti-periplanar conformation that has been observed in related compounds. Furthermore, the conformation of the C=O group with respect to the methyl substituent in the 2-methyl-phenyl ring is syn, as has also been observed in related structures. The amide group makes dihedral angles of 50.3?(3) and 64.6?(3)° with the 2-methyl-phenyl and 2,6-dimethyl-phenyl rings, respectively, while the angle between the planes of the two rings is 14.26?(7)°. The mol-ecules are packed into chains via N-H?O hydrogen bonds. An intramolecular C-H?O hydrogen bond is also observed.

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N-(2,6-Dimethyl-phen-yl)-4-methyl-benzamide.

Project description:In the mol-ecular structure of the title compound, C(16)H(17)NO, the two aromatic rings are close to orthogonal to each other [dihedral angle 78.8?(1)°], while the central -NH-C(=O)- amide core is nearly coplanar with the benzoyl ring, forming a dihedral angle of 3.5?(2)°. Inter-molecular N-H?O hydrogen bonds in the crystal structure link the mol-ecules into infinite chains running along the c axis of the crystal, and a C-H?O interaction also occurs.

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2-Chloro-N-(2,3-dimethyl-phen-yl)benzamide.

Project description:In the title compound, C(15)H(14)ClNO, the N-H and C=O bonds in the amide group are anti to each other. The amide group is inclined at 60.3?(1)° to the chloro-substituted benzoyl ring and at 59.2?(1)° to the dimethyl-substituted aniline ring. The mean planes through the two benzene rings make a dihedral angle of 7.7?(1)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming chains along [010].

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2-Chloro-N-(3,4-dimethyl-phen-yl)benzamide.

Project description:In the title compound, C(15)H(14)ClNO, the conformation of the N-H bond is anti to the meta-methyl group in the aniline ring, while that of the C=O bond is anti to the ortho-chloro group in the benzoyl ring. The mean planes through the two benzene rings make a dihedral angle of 80.8?(2)°. In the crystal, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming column-like chains along the b axis.

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4-Chloro-N-(2,3-dimethyl-phen-yl)benzamide.

Project description:In the title compound, C(15)H(14)ClNO, the ortho- and meta-methyl substituents in the aniline ring are anti to the N-H bond. The dihedral angle between the benzoyl and aniline benzene rings is 95.0?(1)°. N-H?O hydrogen bonds and C-H?? inter-actions link the mol-ecules in the crystal structure.

| S-EPMC3254536 | biostudies-literature

2-Chloro-N-(3,5-dimethyl-phen-yl)benzamide.

Project description:In the structure of the the title compound, C(15)H(14)ClNO, the N-H and C=O bonds are trans to each other and the amide O atom is anti to the ortho-Cl atom in the benzoyl ring. The amide group makes dihedral angles of 61.2?(6) and 42.2?(8)° with the benzoyl and aniline rings, respectively. In the crystal, the mol-ecules are linked into infinite chains by N-H?O hydrogen bonds.

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4-tert-Butyl-N-[(2,6-dimethyl-phen-yl)carbamothio-yl]benzamide.

Project description:The asymmetric unit of the title compound, C(20)H(24)N(2)OS, consists of two crystallographically independent mol-ecules. In each mol-ecule, an intra-molecular N-H?O hydrogen bond forms an S(6) ring motif. The dihedral angles between the terminal benzene rings in the two mol-ecules are 75.52?(7) and 42.80?(7)°. In the crystal, inter-molecular N-H?S inter-actions link the mol-ecules into a chain along the c axis.

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