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Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-?N(1))(nitrato-?O)silver(I) ethanol monosolvate monohydrate.

ABSTRACT: The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N-Ag-N = 151.5?(1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag?O(nitrate) bond [2.717?(4)?Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water mol-ecule, which functions as a hydrogen-bond donor. The water mol-ecule itself is a hydrogen-bond acceptor towards the ethanol solvent mol-ecule. Hydrogen bonds of the type N-H?O give rise to a layer motif parallel to (001).

SUBMITTER: Liu YM 

PROVIDER: S-EPMC3379074 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN(1))(nitrato-κO)silver(I) ethanol monosolvate monohydrate.

Liu Ya-Mei YM   Chen Jing-Huo JH   Yang Guang G   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

The Ag(I) atom in the title compound, [Ag(NO(3))(C(10)H(20)N(4))(2)]·C(2)H(5)OH·H(2)O, is coordinated by the N atoms of two N-heterocycles [N-Ag-N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag⋯O(nitrate) bond [2.717 (4) Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water mol-ecule, which functions as a hydrogen-bond donor. The water mol-ecule itself is a hydrogen-bond  ...[more]

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