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Bis(dicyanamido-?N)tetra-kis-(pyridine-?N)nickel(II).

ABSTRACT: In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni?Ni separation is 8.1068?(10)?Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors.

SUBMITTER: Wohlert S

PROVIDER: S-EPMC3379085 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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Bis(dicyanamido-κN)tetra-kis-(pyridine-κN)nickel(II).

Wöhlert Susanne S Wriedt Mario M Jess Inke I Näther Christian C

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refinement leads to significantly poorer reliability factors. ...[more]

PMID: 22719306

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