Unknown

Dataset Information

0

[(Pyridine-2,6-dicarboxyl-ato)copper(II)]-?-(pyridine-2,6-dicarboxyl-ato)-[bis-(ethyl-enediamine)-copper(II)]-?-(pyridine-2,6-dicarboxyl-ato)-[(pyridine-2,6-dicarboxyl-ato)copper(II)] ethyl-enediamine monosolvate tetra-hydrate.

ABSTRACT: The title compound, [Cu(3)(C(7)H(3)NO(4))(4)(C(2)H(8)N(2))(2)]·C(2)H(8)N(2)·4H(2)O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarb-oxy-lic acid (H(2)dipic) and ethyl-enediamine (en) in an aqueous solution. All of the Cu(II) atoms in the trinuclear centrosymmetric title complex are six-coordinated in a distorted octa-hedral geometry with N(2)O(4) and N(4)O(2) environments for the outer and central Cu(II) atoms, respectively. Various inter-actions, including numerous O-H?O and C-H?O hydrogen bonds and C-O?? stacking of the pyridine and carboxyl-ate groups [O?centroid distances = 3.669?(2) and 3.668?(2)?Å] are observed in the crystal structure.

SUBMITTER: Shokooh Saljooghi A 

PROVIDER: S-EPMC3379149 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

[(Pyridine-2,6-dicarboxyl-ato)copper(II)]-μ-(pyridine-2,6-dicarboxyl-ato)-[bis-(ethyl-enediamine)-copper(II)]-μ-(pyridine-2,6-dicarboxyl-ato)-[(pyridine-2,6-dicarboxyl-ato)copper(II)] ethyl-enediamine monosolvate tetra-hydrate.

Shokooh Saljooghi Amir A   Amiri Rudbari Hadi H   Nicolò Francesco F   Zahmati Maliheh M   Delavar Mendi Fatemeh F  

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

The title compound, [Cu(3)(C(7)H(3)NO(4))(4)(C(2)H(8)N(2))(2)]·C(2)H(8)N(2)·4H(2)O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarb-oxy-lic acid (H(2)dipic) and ethyl-enediamine (en) in an aqueous solution. All of the Cu(II) atoms in the trinuclear centrosymmetric title complex are six-coordinated in a distorted octa-hedral geometry with N(2)O(4) and N(4)O(2) environments for the outer and central Cu(II) atoms, respectively. Various inter-actions, including  ...[more]

Similar Datasets

Unknown Hexaaqua-nickel(II) tetra-aqua-bis-(?-pyridine-2,6-dicarboxyl-ato)bis-(pyridine-2,6-dicarboxyl-ato)trinickelate(II) octa-hydrate.
| S-EPMC3007465 | biostudies-literature
Unknown Aqua-(4-hydroxy-pyridine-2,6-dicarboxyl-ato)(1,10-phenanothroline)copper(II) 4.5-hydrate.
| S-EPMC2915167 | biostudies-literature
Unknown Diaqua-(2,2'-bipyridine-5,5'-dicarboxyl-ato-?N,N')(ethyl-enediamine-?N,N')copper(II) 2.5-hydrate.
| S-EPMC2959425 | biostudies-literature
Unknown Aqua-(1H-benzimidazole-?N)(pyridine-2,6-dicarboxyl-ato-?O,N,O)copper(II) 0.75-hydrate.
| S-EPMC2979051 | biostudies-literature
Unknown Acridinium (6-carboxy-pyridine-2-carboxyl-ato)(pyridine-2,6-dicarboxyl-ato)zincate(II) penta-hydrate.
| S-EPMC2968778 | biostudies-literature
Unknown Benzene-1,3-diammonium bis-(pyridine-2,6-dicarboxyl-ato)nickelate(II) penta-hydrate.
| S-EPMC3051631 | biostudies-literature
Unknown Tetra-μ-aqua-octaaqua-bis(μ-4-chloro-pyridine-2,6-dicarboxyl-ato)bis-(4-chloro-pyridine-2,6-dicarboxyl-ato)tri-cobalt(II)disodium(I) bis-[triaqua-bis(4-chloro-pyridine-2,6-dicarboxyl-ato)cobalt(II)] hexa-hydrate.
| S-EPMC2915174 | biostudies-literature
Unknown Tetra-kis(1,10-phenanthroline)bis-(?-pyridine-2,6-dicarboxyl-ato)(pyridine-2,6-di-carboxyl-ato)dicopper(II)terbium(III) nitrate tetra-hydrate.
| S-EPMC3414140 | biostudies-literature
Unknown Creatininium bis-(pyridine-2,6-dicarboxyl-ato)chromate(III) pyridine-2,6-dicarboxylic acid hexa-hydrate.
| S-EPMC2959312 | biostudies-literature
Unknown (2,2'-Bipyridine)(pyridine-2,6-dicarboxyl-ato)oxidovanadium(IV) ethanol monosolvate.
| S-EPMC3051467 | biostudies-literature