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4-[(E)-({4-[(4-Amino-phen-yl)sulfon-yl]phen-yl}imino)-meth-yl]phenol ethanol monosolvate.

ABSTRACT: In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17?(7) and 77.06?(7)° with respect to the aniline groups. The sulfonyl group make dihedral angles of 44.89?(13) and 59.16?(12)° with the adjacent aniline groups. In the crystal, a two-dimensional polymeric network parallel to (010) is formed by N-H?O, O-H?N and O-H?O hydrogen bonds. There also exist ?-? inter-actions with a distance of 3.5976?(18)?Å between the centroids of hy-droxy-phenyl rings.

SUBMITTER: Afzal S

PROVIDER: S-EPMC3379368 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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4-[(E)-({4-[(4-Amino-phen-yl)sulfon-yl]phen-yl}imino)-meth-yl]phenol ethanol monosolvate.

Afzal Sadaf S Akhter Zareen Z Tahir M Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

In the title compound, C(19)H(16)N(2)O(3)S·C(2)H(6)O, the 4-hy-droxy-benzyl-idene group is oriented at dihedral angles of 73.17 (7) and 77.06 (7)° with respect to the aniline groups. The sulfonyl group make dihedral angles of 44.89 (13) and 59.16 (12)° with the adjacent aniline groups. In the crystal, a two-dimensional polymeric network parallel to (010) is formed by N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds. There also exist π-π inter-actions with a distance of 3.5976 (18) Å between the centroids o ...[more]

PMID: 22719566

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