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(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide.

ABSTRACT: The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13?(13)°. In the crystal, mol-ecules are linked through pairs of N-H?O and O-H?S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H?N, O-H?O and C-H?? inter-actions are also present.

SUBMITTER: Jacob JM 

PROVIDER: S-EPMC3379435 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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(2E)-2-(5-Bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-N-phenyl-hydrazine-carbo-thio-amide.

Jacob Jinsa Mary JM   Sithambaresan M M   Kurup M R Prathapachandra MR  

Acta crystallographica. Section E, Structure reports online 20120523 Pt 6

The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio-amide form. The two rings in the mol-ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol-ecules are linked through pairs of N-H⋯O and O-H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra-molecular N-H⋯N, O-H⋯O and C-H⋯π inter-actions are also present. ...[more]

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