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3,4,7,8-Tetra-methyl-1,10-phenanthrolin-1-ium nitrate monohydrate.

ABSTRACT: In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (-)·H(2)O, the tetra-methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol-ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol-ecule are linked by O-H?O and N-H?O hydrogen bonds into a sheet parallel to the bc plane. ?-? stacking between phenanthroline ring systems is observed in the crystal structure, the centroid-centroid distance being 3.4745?(6)?Å.

SUBMITTER: Zhang KJ

PROVIDER: S-EPMC3379486 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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3,4,7,8-Tetra-methyl-1,10-phenanthrolin-1-ium nitrate monohydrate.

Zhang Ke-Jie KJ Zhang Yan-Fang YF

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (-)·H(2)O, the tetra-methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol-ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol-ecule are linked by O-H⋯O and N-H⋯O hydrogen bonds into a sheet parallel to the bc plane. π-π stacking between phenanthroline ring systems is observed in the crystal struct ...[more]

PMID: 22719684

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