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ABSTRACT:
SUBMITTER: Bahojb Noruzi E
PROVIDER: S-EPMC3393176 | biostudies-other | 2012 Jul
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20120613 Pt 7
In the title compound, (C₁₄H₁₃N₂)[FeCl₄]·CH₃OH, the 2,9-dimethyl-1,10-phenanthrolin-1-ium cation, FeCl₄ ⁻ anion and methanol solvent mol-ecule lie on a twofold rotation axis. Due to symmetry, the H atom on the N atom of the cation is half-occupied. In the anion, the Fe(III) atom has a tetra-hedral geometry. H atoms of the methanol mol-ecule are disordered over two sets of sites around the twofold axis. In the crystal, π-π contacts between the pyridine rings and between the pyridine and benzene r ...[more]