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Oxido[N-(2-oxidobenzyl-idene-?O)leucinato-?²N,O](1,10-phenanthroline-?²N,N')vanadium(IV).

ABSTRACT: In the title V(IV) complex, [VO(C??H??NO?)(C??H?N?)], the oxidovanadium cation is N,N'-chelated by a 1-10-phenanthroline ligand and N,O,O'-chelated by a Schiff base anion in a distorted octa-hedral geometry. Weak inter-molecular C-H?O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81?Å³.

SUBMITTER: Wang CY

PROVIDER: S-EPMC3393178 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

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Oxido[N-(2-oxidobenzyl-idene-κO)leucinato-κ²N,O](1,10-phenanthroline-κ²N,N')vanadium(IV).

Wang Cheng-Yuan CY Jing Bu-Qin BQ Dong Jian-Fang JF Li Lian-Zhi LZ

Acta crystallographica. Section E, Structure reports online 20120613 Pt 7

In the title V(IV) complex, [VO(C₁₃H₁₅NO₃)(C₁₂H₈N₂)], the oxidovanadium cation is N,N'-chelated by a 1-10-phenanthroline ligand and N,O,O'-chelated by a Schiff base anion in a distorted octa-hedral geometry. Weak inter-molecular C-H⋯O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81 Å³. ...[more]

PMID: 22807746

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Oxido{N-[(2-oxido-1-naphthyl-?O)methyl-idene]asparaginato-?O,N}(1,10-phenanthroline-?N,N')vanadium(IV) N,N-dimethyl-formamide monosolvate.

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