Unknown

Dataset Information

0

Tris(1,10-phenanthroline-?(2)N,N')iron(II) bis-(1,1-dicyano-2-eth-oxy-2-oxoethanide).


ABSTRACT: The title compound, [Fe(C(12)H(8)N(2))(3)](C(6)H(5)N(2)O(2))(2), consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth-oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521?(13) for the major component]. In the complex cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. Two intra-molecular C-H?N hydrogen bonds occur in the complex cation. The crystal structure is mainly stabilized by Coulombic inter-actions. Weak intermolecular C-H?N inter-actions are also observed.

SUBMITTER: Cai ZM 

PROVIDER: S-EPMC3393210 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

altmetric image

Publications

Tris(1,10-phenanthroline-κ(2)N,N')iron(II) bis-(1,1-dicyano-2-eth-oxy-2-oxoethanide).

Cai Zhan-Mao ZM   Zhan Shu-Zhong SZ  

Acta crystallographica. Section E, Structure reports online 20120620 Pt 7


The title compound, [Fe(C(12)H(8)N(2))(3)](C(6)H(5)N(2)O(2))(2), consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth-oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521 (13) for the major component]. In the complex cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. Two intra-molecular C-H⋯N hydrogen bonds occur in the complex cation.  ...[more]

Similar Datasets

| S-EPMC3588335 | biostudies-other
| S-EPMC3152094 | biostudies-literature
| S-EPMC3588769 | biostudies-literature
| S-EPMC3238718 | biostudies-literature
| S-EPMC3200904 | biostudies-other
| S-EPMC2961299 | biostudies-literature
| S-EPMC2959834 | biostudies-literature
| S-EPMC3344293 | biostudies-literature
| S-EPMC2959559 | biostudies-literature
| S-EPMC4331886 | biostudies-literature