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Tris(1,10-phenanthroline-?(2)N,N')iron(II) bis-(1,1-dicyano-2-eth-oxy-2-oxoethanide).

ABSTRACT: The title compound, [Fe(C(12)H(8)N(2))(3)](C(6)H(5)N(2)O(2))(2), consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth-oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521?(13) for the major component]. In the complex cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. Two intra-molecular C-H?N hydrogen bonds occur in the complex cation. The crystal structure is mainly stabilized by Coulombic inter-actions. Weak intermolecular C-H?N inter-actions are also observed.

SUBMITTER: Cai ZM

PROVIDER: S-EPMC3393210 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

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Tris(1,10-phenanthroline-κ(2)N,N')iron(II) bis-(1,1-dicyano-2-eth-oxy-2-oxoethanide).

Cai Zhan-Mao ZM Zhan Shu-Zhong SZ

Acta crystallographica. Section E, Structure reports online 20120620 Pt 7

The title compound, [Fe(C(12)H(8)N(2))(3)](C(6)H(5)N(2)O(2))(2), consists of one [Fe(phen)(3)](2+) cation (phen = 1,10-phenanthroline) and two 1,1-dicyano-2-eth-oxy-2-oxoethanide anions. Five atoms of the anion are disordered over two positions [site occupancy = 0.521 (13) for the major component]. In the complex cation, the Fe(II) atom is coordinated by six N atoms from three phen ligands in a distorted octa-hedral geometry. Two intra-molecular C-H⋯N hydrogen bonds occur in the complex cation. ...[more]

PMID: 22807778

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