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Dibromido(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')(dimethyl sulfoxide-?O)cadmium.

ABSTRACT: In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra-molecular C-H?O hydrogen bond occurs between the DMBP and DMSO ligands. ?-? stacking between pyridine rings [centroid-centroid distances = 3.682?(3) and 3.598?(3)?Å] is observed in the crystal.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3393245 | biostudies-other | 2012 Jul

REPOSITORIES: biostudies-other

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Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(dimethyl sulfoxide-κO)cadmium.

Shirvan Sadif A SA Haydari Dezfuli Sara S

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra-molecular C-H⋯O hydrogen bond occurs between the DMBP and DMSO ligands. π-π stacking between pyridine rings [centroid-centroid distances = 3.682 (3) and 3.598 (3) Å] is observed in the crystal. ...[more]

PMID: 22807705

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