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N-(2,4,6-Trimethyl-phen-yl)-1,3-thia-zol-2-amine.

ABSTRACT: In the title compound, C(12)H(14)N(2)S, the dihedral angle between the 1,3,5-trimethyl-benzene and 1,3-thia-zol-2-amine groups is 73.15?(4)°. In the crystal, inversion dimers linked by pairs of N-H?N hydrogen bonds generate R(2) (2)(8) loops.

SUBMITTER: Babar A

PROVIDER: S-EPMC3414355 | biostudies-other | 2012 Aug

REPOSITORIES: biostudies-other

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N-(2,4,6-Trimethyl-phen-yl)-1,3-thia-zol-2-amine.

Babar Ayesha A Munawar Munawar Ali MA Tahir M Nawaz MN Khan Ather Farooq AF Tariq Muhammad Ilyas MI

Acta crystallographica. Section E, Structure reports online 20120714 Pt 8

In the title compound, C(12)H(14)N(2)S, the dihedral angle between the 1,3,5-trimethyl-benzene and 1,3-thia-zol-2-amine groups is 73.15 (4)°. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds generate R(2) (2)(8) loops. ...[more]

PMID: 22904888

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4-(2,4,6-Trimethyl-benz-yl)-1,3-thia-zol-2-amine.

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N-(1,3-Thia-zol-2-yl)-2-(2,4,6-trimethyl-phen-yl)acetamide.

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N-(2,4-Dichloro-phen-yl)-1,3-thia-zol-2-amine.

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Project description:In the title compound, C(23)H(23)N(5)S, the thia-zole ring and pyrimidine ring are almost coplanar, making a dihedral angle of 4.02?(9)°. in the crystal, weak inter-molecular N-H?N inter-actions link pairs of molecules into centrosymmetric dimers.

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Project description:The title compound, C(18)H(16)ClN(3)S, adopts an extended mol-ecular structure. The thia-zole ring is inclined by 9.2?(1) and 15.3?(1)° with respect to the chloro-phenyl and 4-(dimethyl-amino)-phenyl rings, respectively, while the benzene ring planes make an angle of 19.0?(1)°. A weak inter-molecular C-H?? contact is observed in the crystal structure.

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Project description:In the title compound, C(11)H(9)FN(2)OS, the 1,3-thia-zole ring is planar (r.m.s. deviation = 0.007?Å) and forms a dihedral angle of 73.75?(5)° with the benzene ring. In the crystal, mol-ecules are linked via pairs of N-H?N and C-H?F hydrogen bonds into chains along [100].

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2-(4-Chloro-phen-yl)-N-(1,3-thia-zol-2-yl)acetamide.

Project description:In the title compound, C(11)H(9)ClN(2)OS, the thia-zole ring is nearly planar (r.m.s. deviation = 0.003 Å) and forms a dihedral angle of 64.18 (7)° with the bezene ring. In the crystal, inversion dimers linked by pairs of N-H⋯N(t) (t = thia-zole) hydrogen bonds generate R(2) (2)(8) loops.

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2-(2,6-Dichloro-phen-yl)-N-(1,3-thia-zol-2-yl)acetamide.

Project description:In the title compound, C11H8Cl2N2OS, the mean plane of the dichloro-phenyl ring is twisted by 79.7 (7)° from that of the thia-zole ring. In the crystal, molecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers which stack along the a-axis direction.

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N-(3-Meth-oxy-phen-yl)-4-{4-methyl-2-[(meth-yl)(4-methyl-phen-yl)amino]-1,3-thia-zol-5-yl}pyrimidin-2-amine.

Project description:The asymmetric unit of the title compound, C(23)H(23)N(5)OS, contains two independent mol-ecules. In one mol-ecule, the thia-zole and pyrimidine rings are almost co-planar, making a dihedral angle of 2.48?(8)°. In the other mol-ecule, the corresponding dihedral angle is 12.82?(8)°. The crystal structure is stabilized by weak inter-molecular N-H?N and C-H?O inter-actions that extend along the b axis.

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