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2,3,5-Triphenyl-2H-tetra-zol-3-ium bromide ethanol monosolvate.

ABSTRACT: In the title compound, C(19)H(15)N(4) (+)·Br(-)·C(2)H(5)OH, the tetra-zole ring makes dihedral angles of 57.44?(9), 50.92?(9) and 4.65?(8)° with the attached phenyl rings. In the crystal, the cation and the anion are linked to each other by inter-molecular C-H?Br hydrogen bonds into an infinite chain along the b axis. The anion and the ethanol solvent mol-ecule are linked by an O-H?Br hydrogen bond. The crystal studied was an inversion twin with a refined component ratio of 0.632?(5):0.368?(5).

SUBMITTER: Fun HK

PROVIDER: S-EPMC3415007 | biostudies-other | 2012 Aug

REPOSITORIES: biostudies-other

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2,3,5-Triphenyl-2H-tetra-zol-3-ium bromide ethanol monosolvate.

Fun Hoong-Kun HK Chia Tze Shyang TS Mostafa Gamal A E GA Hefnawy Mohamed M MM Abdel-Aziz Hatem A HA

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

In the title compound, C(19)H(15)N(4) (+)·Br(-)·C(2)H(5)OH, the tetra-zole ring makes dihedral angles of 57.44 (9), 50.92 (9) and 4.65 (8)° with the attached phenyl rings. In the crystal, the cation and the anion are linked to each other by inter-molecular C-H⋯Br hydrogen bonds into an infinite chain along the b axis. The anion and the ethanol solvent mol-ecule are linked by an O-H⋯Br hydrogen bond. The crystal studied was an inversion twin with a refined component ratio of 0.632 (5):0.368 (5). ...[more]

PMID: 22904994

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