Ontology highlight
ABSTRACT:
SUBMITTER: Liu L
PROVIDER: S-EPMC3438900 | biostudies-other | 2012 Jul
REPOSITORIES: biostudies-other
Angewandte Chemie (International ed. in English) 20120612 29
Golden Cascade: With a tethered, electron-rich arene as the internal nucleophile, a gold-catalyzed amide cyclization to an alkyne initiates a cascade process that ends with a Ferrier rearrangement. Electron-rich arene-bearing hexahydroquinolizin-2-ones are formed in good yields and can be converted into indole alkaloids in only a few steps. ...[more]