(?(6)-Benzene)-(benzyl-diphenyl-phos-phane)dichloridoruthenium(II).

ABSTRACT: In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa-hedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(?(6)-benzene) = 1.6894?(11)?Å, Ru-P = 2.3466?(6), Ru-Cl(avg.) = 2.4127?(7)?Å; Cl-Ru-Cl = 88.07?(2) and Cl-Ru-P = 82.77?(2), 87.65?(2)°. The effective cone angle for the benzyl-diphenyl-phosphane was calculated to be 143°. In the crystal C-H?Cl and C-H?? inter-actions are observed.

SUBMITTER: Muller A 

PROVIDER: S-EPMC3470126 | biostudies-other | 2012 Oct

REPOSITORIES: biostudies-other