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(?(6)-Benzene)-(benzyl-diphenyl-phos-phane)dichloridoruthenium(II).

ABSTRACT: In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa-hedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(?(6)-benzene) = 1.6894?(11)?Å, Ru-P = 2.3466?(6), Ru-Cl(avg.) = 2.4127?(7)?Å; Cl-Ru-Cl = 88.07?(2) and Cl-Ru-P = 82.77?(2), 87.65?(2)°. The effective cone angle for the benzyl-diphenyl-phosphane was calculated to be 143°. In the crystal C-H?Cl and C-H?? inter-actions are observed.

SUBMITTER: Muller A

PROVIDER: S-EPMC3470126 | biostudies-other | 2012 Oct

REPOSITORIES: biostudies-other

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(η(6)-Benzene)-(benzyl-diphenyl-phos-phane)dichloridoruthenium(II).

Muller Alfred A Davis Wade L WL

Acta crystallographica. Section E, Structure reports online 20120901 Pt 10

In the title compound, [RuCl(2)(C(6)H(6))(C(19)H(17)P)], the Ru(II) atom has a distorted pseudo-octa-hedral coordination environment with the metrical parameters around the metallic core as Ru-centroid(η(6)-benzene) = 1.6894 (11) Å, Ru-P = 2.3466 (6), Ru-Cl(avg.) = 2.4127 (7) Å; Cl-Ru-Cl = 88.07 (2) and Cl-Ru-P = 82.77 (2), 87.65 (2)°. The effective cone angle for the benzyl-diphenyl-phosphane was calculated to be 143°. In the crystal C-H⋯Cl and C-H⋯π inter-actions are observed. ...[more]

PMID: 23125570

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