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Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl-methyl-idene)ethanamine-?(3)N,N',N'']manganese(II) monohydrate.

ABSTRACT: In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison ? parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl-methyl-idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O?O distances of 3.103?(7)?Å and O?Cl distances of 3.240?(3) and 3.482?(4)?Å suggest that hydrogen bonding is responsible for the stabilization of the crystal packing.

SUBMITTER: Tinguiano D

PROVIDER: S-EPMC3470139 | biostudies-other | 2012 Oct

REPOSITORIES: biostudies-other

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Dichlorido[2-(pyridin-2-yl)-N-(pyridin-2-yl-methyl-idene)ethanamine-κ(3)N,N',N'']manganese(II) monohydrate.

Tinguiano Daniel D Thiam Ibrahima Elhadj IE Dieng Moussa M Gaye Mohamed M Retailleau Pascal P

Acta crystallographica. Section E, Structure reports online 20120908 Pt 10

In the title complex, [MnCl(2)(C(13)H(13)N(3))]·H(2)O, the Mn(II) atom is in a distorted square-pyramidal environment, with an Addison τ parameter of 0.037. The coordination geometry is defined by three N-atom donors from the tridentate 2-(pyridin-2-yl)-N-(pyridin-2-yl-methyl-idene)ethanamine ligand and two terminal Cl atoms. Although the H atoms of the lattice water molecule were not located, O⋯O distances of 3.103 (7) Å and O⋯Cl distances of 3.240 (3) and 3.482 (4) Å suggest that hydrogen bond ...[more]

PMID: 23125583

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