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Di-?-chlorido-bis-{chlorido[2,3-dimethyl-N-(pyridin-2-yl-methyl-idene)aniline-?(2)N,N']mercury(II)}.

ABSTRACT: In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino-pyridine ligand and three Cl atoms. The benzene and pyridine rings are oriented at a dihedral angle of 56.7?(6)°. The crystal packing is stabilized by C-H?Cl hydrogen bonds and ?-? inter-actions between the pyridine rings [centroid-centroid distance = 3.796?(6)?Å].

SUBMITTER: Hoseyni SJ

PROVIDER: S-EPMC3470166 | biostudies-other | 2012 Oct

REPOSITORIES: biostudies-other

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Di-μ-chlorido-bis-{chlorido[2,3-dimethyl-N-(pyridin-2-yl-methyl-idene)aniline-κ(2)N,N']mercury(II)}.

Hoseyni Seyed Jalal SJ Talei Bavil Olyai Mohamad Reza MR Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20120922 Pt 10

In the centrosymmetric binuclear molecule of the title complex, [Hg(2)Cl(4)(C(14)H(14)N(2))(2)], the five-coordinated Hg(II) ions have a distorted square-pyramidal geometry defined by two N atoms belonging to the chelating imino-pyridine ligand and three Cl atoms. The benzene and pyridine rings are oriented at a dihedral angle of 56.7 (6)°. The crystal packing is stabilized by C-H⋯Cl hydrogen bonds and π-π inter-actions between the pyridine rings [centroid-centroid distance = 3.796 (6) Å]. ...[more]

PMID: 23125610

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