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Enantiomeric natural products: occurrence and biogenesis.


ABSTRACT: In nature, chiral natural products are usually produced in optically pure form-however, occasionally both enantiomers are formed. These enantiomeric natural products can arise from a single species or from different genera and/or species. Extensive research has been carried out over the years in an attempt to understand the biogenesis of naturally occurring enantiomers; however, many fascinating puzzles and stereochemical anomalies still remain.

SUBMITTER: Finefield JM 

PROVIDER: S-EPMC3498912 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

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Enantiomeric natural products: occurrence and biogenesis.

Finefield Jennifer M JM   Sherman David H DH   Kreitman Martin M   Williams Robert M RM  

Angewandte Chemie (International ed. in English) 20120503 20


In nature, chiral natural products are usually produced in optically pure form-however, occasionally both enantiomers are formed. These enantiomeric natural products can arise from a single species or from different genera and/or species. Extensive research has been carried out over the years in an attempt to understand the biogenesis of naturally occurring enantiomers; however, many fascinating puzzles and stereochemical anomalies still remain. ...[more]

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