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Bis(chlorido)(dimethyl-sulfoxide-?O)barium(II).

ABSTRACT: The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl-sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa-hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter-connected by the DMSO mol-ecules, forming a three-dimensional network.

SUBMITTER: Gschwind F

PROVIDER: S-EPMC3515089 | biostudies-other | 2012 Nov

REPOSITORIES: biostudies-other

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Bis(chlorido)(dimethyl-sulfoxide-κO)barium(II).

Gschwind Fabienne F Jansen Martin M

Acta crystallographica. Section E, Structure reports online 20121003 Pt 11

The title compound, [BaCl(2)(C(2)H(6)SO)], forms a Ba(6)Cl(9) cluster in which the BaCl(2) units are connected via dimethyl-sulfoxide (DMSO) and chloride bridges. The central Cl atom of the Ba(6)Cl(9) cluster is located on a threefold inversion axis and is coordinated octa-hedrally to six barium cations. In the crystal, the clusters are arranged in rows, which are inter-connected by the DMSO mol-ecules, forming a three-dimensional network. ...[more]

PMID: 23284316

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